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I loved my first meal in Naraya restaurant: it was good food and the service was good and the free chipotle ramen wasÂ .Couple rescued after being swept away by raging floodwaters in Norman
Boaters made it to the couple in time to save them after the vessel they were on capsized in flood waters off of U.S. 41 east of Norman
NORMAN – A couple from San Antonio who were on their way to visit family for a short time has been found safe and sound after a horrific incident happened Friday night.
Boaters made it to the couple in time to save them after the vessel they were on capsized in flood waters off of U.S. 41 east of Norman.
Shaila Weiss of KENS reported that the couple is now with family and are on their way back to San Antonio.
When the incident happened, the couple did not know there was a river a few feet away. Both have been on the water their entire lives.
Weiss reports that the couple and the boat are very lucky to be alive.Preliminary results from quantitative structure-activity relationship modeling of inhibition of serine and cysteine proteases: a novel predictive tool for the discovery of quinone methide phosphonates.
The transformation of phosphonooxymethylketone (PMK), an acylated methyl ketone with little antiviral activity, to its quinone methide form (QM), a potent inhibitor of cysteine proteases, was studied computationally (using Density Functional Theory-M06) to explore the applicability of such model for quantitative structure-activity relationship (QSAR) studies. PMK, having a single P-O bond, is transformed (i) to dioxa-PMK by 1,3-addition of (O═C-P-O)n moiety of phosphonic acid (where n>or=1), or 2,5-addition of (O═C-P-O)2 moiety of phosphinic acid (where n=2), or by (ii) to QM by nucleophilic addition of the vinyl (C=C-P-O)n moiety of phosphonic acid (where n>or=1) or phosphinic acid (where n=2). All the P-O tautomers are possible depending on the chemical shift of (31)P nucleus. The nucleophilic
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