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19/02/2010 · Download Arial Black, ARBLI.ttf Italic font for Windows, free 49984 Various fonts to dowwnload arial.ttf.The present invention relates to an improved process for the production of stable aqueous solutions of alkali metal silicates.
Alkali metal silicates have long been used as builders, fillers, detergent builders and anti-caking agents for detergents, and may be used as an anti-caking agent for briquettes. The alkali metal silicates contain in particular alkali metal silicate species which have the general chemical formula (M1/2)x(SiO2)y wherein M represents the alkali metal ion, x and y are integers. In the production of these alkali metal silicates, a reaction is usually conducted between an alkali metal silicate and an alkali metal hydroxide in an aqueous reaction medium in the presence of a dispersant, the dispersed phase being separated from the reaction mixture by means of an appropriate separating device before the solution is subjected to crystallization. During the crystallization, a portion of the alkali metal silicate which is present in a dissolved or dispersible form and which is separated by means of the separating device crystallizes out as solid crystals, while another portion, namely the particulate alkali metal silicate which is present in an undissolved state and is separated from the reaction mixture by means of the separating device, is present in the crystallizing solution in a dispersible form and is converted into a stable, crystalline solid.
Usually, the alkali metal silicate which crystallizes out, referred to as the mother liquor, is either recycled directly to the reaction, or is discharged therefrom.
When the mother liquor is recycled to the reaction, the reaction should be carried out at a temperature which is below the temperature at which the mother liquor crystallizes so that the alkali metal silicate which crystallizes out, and the alkali metal hydroxide which reacts with it, do not crystallize out before the reaction is complete. Such prior art processes are described for example in U.S. Pat. No. 4,011,383, U.S. Pat. No. 4
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